If you have 5 models finished, why not just upload all of them? Yes, it's true that certain categories will tend to sell better than others, but it also depends on the quality of the models and how often you can add new content to your store.
However, if you only have 1 single model in your portfolio, your chances of making sales are minimal even if it's a good model. Think about the fact that there are probably thousands of good models in every category already. Start out by modeling what you know best and what you like to work with. As your portfolio grows and you analyze the analytics more closely, maybe then you can decide on a different category to focus your efforts or maybe stick with what you enjoy.. Just don't expect sales to happen quickly with only a few products. A single model could take months before someone discovers it and decides to purchase it.